English
聯系我們
網站地圖
郵箱
舊版回顧



上海硅酸鹽所在鋰電池安全性提升研究中取得進展

文章來源:上海硅酸鹽研究所   發布時間:2019-05-10  【字號:     】  

  最近,中國科學院上海硅酸鹽研究所研究員溫兆銀團隊通過離子導電型引發劑實現了凝膠聚合物電解質的原位制備,該凝膠聚合物電解質具有優異的耐火性能,基于該電解質組裝的固態鋰電池在同時承受剪切與火燒條件(火焰溫度528)下仍能為發光二極管陣列供電,使鋰電池的安全性大大提高。相關工作申請了中國發明專利,主要研究結果以In Situ Generated Fireproof Gel Polymer Electrolyte with Li6.4Ga0.2La3Zr2O12 As Initiator and Ion-Conductive Filler 為題發表在國際期刊《先進能源材料》(Advanced Energy Materials上,論文第一作者為上海硅酸鹽所在讀博士研究生徐東,導師為溫兆銀。

  凝膠聚合物電解質(GPE)在一定程度上兼具固態聚合物電解質(SPE)的高安全性與液態電解質高離子電導率的優點,被認為是當前最適合實際應用的一種電解質體系。目前研究較多的是基于聚偏氟乙烯(PVDF)及其衍生物的凝膠聚合物電解質體系。然而凝膠電解質中仍然含有一定量的可燃性液態電解質,存在安全隱患。為進一步提高其安全性能以及電化學性能,科研工作者做了大量的研究工作,主要包括有機-有機共混改性、有機-無機復合改性、物理/化學交聯改性等。但大多數文獻并未對凝膠聚合物電解質的安全性能進行詳細報道。另一方面,在目前常用的相轉換法等凝膠聚合物電解質的制備過程中,使用了大量揮發性有機溶劑,既污染環境,又增加成本,且制備過程繁瑣。采用原位交聯聚合制備的方法可以避免或減輕上述問題。

  溫兆銀團隊以石榴石型固體電解質(Li6.4Ga0.2La3Zr2O12)為引發劑和離子導電型填料,在聚偏氟乙烯-六氟丙烯共聚物(PVDF-HFP)的磷酸三乙酯/氟代碳酸乙烯酯(TEP/FEC)混合溶液中引發PVDF-HFP的脫氟和交聯過程,從而實現凝膠聚合物電解質的原位制備,并對凝膠轉變過程的機理進行了深入研究。優化后的凝膠聚合物電解質在20時離子電導率達到1.83×10-3 S cm-1,室溫下電化學穩定窗口4.75V。該凝膠聚合物電解質具有優異的耐火性能,由其組裝的固態鋰電池具有較高的安全性。基于該凝膠聚合物電解質的三元鋰電池表現出較好的循環穩定性。該工作提供了采用防火型凝膠電解質可獲得優良的離子電導率以及保證凝膠聚合物電解質和相應鋰電池高安全性的研究新思路。

  相關工作得到國家重點研發計劃、國家自然科學基金面上項目的資助。

  論文鏈接

 

  防火型凝膠聚合物電解質組成與結構示意圖及基于該凝膠聚合物電解質的軟包鋰電池的剪切和燃燒實驗




(責任編輯:葉瑞優)

附件:

專題推薦

相關新聞


© 1996 - 中國科學院 版權所有 京ICP備05002857號  京公網安備110402500047號  聯系我們

地址:北京市三里河路52號 郵編:100864

购彩网www.08gcw.com www.685054.com | www.876541.com | 354765.com | 043311.com | www.kp2.com | www.xx44.com | www.45af.com | www.27559.com | www.022940.com | www.190286.com | www.326544.com | www.442296.com | www.570160.com | www.956711.com | 089433.com | 132503.com | 240933.com | www.cp6543.cc | www.rg45.com | www.05fz.com | www.76nv.com | www.3377.pw | www.9968.biz | www.66344.cc | www.044310.com | www.198049.com | www.380639.com | www.557122.com | www.652092.com | www.865678.com | 076694.com | 731431.com | www.cp367.com | www.mb36.cc | www.5826.cc | www.30939.cc | www.62658.com | www.100824.com | www.166122.cc | www.581858.com | www.623004.com | www.885897.com | 127843.com | cl14.com | rc20.com | www.cai628.cc | www.pj14.cc | www.66at.com | www.2172.cn | www.48843.cc | www.038918.com | www.128617.com | www.203143.com | www.310644.com | www.608911.com | www.708682.com | www.822905.com | 纵横彩票www.903839.com | www.sc48.com | www.53ro.com | www.570.in | www.16313.com | www.63351.cc | www.109179.com | www.202802.com | www.263909.com | www.382938.com | www.625072.com | www.716167.com | www.788739.com | www.227777.com | 170636.com | 212298.com | 897778.com--897778.com | AKW彩票www.akw0.com | www.cp2388.com | www.rq17.com | www.a10.tv | www.15vq.com | www.35qv.com | www.76eh.com | www.535.site | www.8667.loan | www.44281.com | www.86176.com | www.051667.com | www.127731.com | www.190296.com | www.332492.com | www.381884.com | www.589850.com | www.675487.com | www.726028.com | www.804689.com | 149395.com | www.cp7895.com | www.mz17.com | www.1491.top | www.22055.cc | www.59159.com | www.73812.com | www.105337.com | www.183951.com | www.365975.com | www.587918.com | 99980.com | 585394.com | www.396548.com | www.590448.com | www.655361.com | www.917955.com | www.929933.com | www.941946.com | 358766.com | 967437.com | 4593.cc | 发彩www.50732c.com | www.ci35.com | www.d59.club | www.s34.me | www.47mk.com | www.64dk.com | www.89di.com | www.732.in | www.6429.cc | www.9489.win | www.38013.com | www.68835.com | www.087085.com | www.135305.com | www.283153.com | www.358230.com | www.552926.com | www.590499.com | www.650041.com | www.860827.com | 828501.com | 74495.com | 605340.com | 809582.com | 275953.com | 526030.com | 500彩票www.50026e.com | www.af3.com | www.gp73.com | www.hc13.cc | www.292922.com | www.322800.com | www.373091.com | www.663559.com | www.898815.com | www.906168.com | www.901995.com | www.893418.com | www.881174.com | www.969143.com | www.954381.com | www.950116.com | www.954187.com | www.952636.com | www.935871.com | www.906885.com | www.900788.com | www.905598.com | www.951254.com | www.947615.com | www.916180.com | www.897653.com | 456071.com | 611850.com | www.cai0266.com | www.018399.com | www.732629.com | www.960412.com | www.949623.com | www.932300.com | www.938623.com | www.897562.com | 947370.com | 973490.com | 489993.com | www.97799.com | 福利彩票www.99677l.com | 600万彩票www.187397.com | 万彩网www.wcp686.com | www.ed.com | www.ef24.com | www.vj10.com | www.zx08.com | www.42va.com | www.001580.com | www.073105.com | www.190622.com | www.233755.com | www.348352.com | www.577520.com | www.596872.com | www.717036.com | www.717681.com | www.793579.com | www.800621.com | 006274.com | 608525.com | qx08.com | 7845.biz | 717221.cc | www.790964.com | www.556981.com | www.610679.com | www.830513.com | www.977585.com | www.954554.com | 000904.com | 772304.com | 917056.com | 700990.com | k28.xyz | 049861.com | 731079.com | www.wi0.cc | www.ch91.com | www.nq88.com | www.wt90.com | www.ul88.com | www.rw57.com | www.np29.com | www.4eg.cc | www.1205.top | www.2706.pw | www.3908.com | www.1444.cm | www.23968.com | www.31008.com | www.22396.cc | www.8988.tv | www.20079.com | www.32383.com | www.324344.com | www.358547.com | www.562535.com | www.569208.com | www.862390.com | www.940043.com | www.899641.com | www.876431.com | 974804.com | 951794.com | 110235.com | 951457.com | 5299.top | 948657.com | 947656.com | 897319.com | 973487.com | 965954.com | 960184.com | 979065.com | 739244.com | 358364.com | 03788.com | 739481.com | 520806.com | 788185.com | 75088.com | 639436.com | 489552.com | www.ep45.com | www.nb67.com | www.19fc.cc | www.l91.club | www.ry18.com | www.rq74.com | www.ko80.com | www.rv17.com | www.fq04.com | www.mu88.com | www.xh31.cc | www.ri59.com | www.13sr.com | www.v62.cn | www.s13.biz | www.zc03.cc | www.uk24.com | www.nv02.com | www.03rw.com | www.zz23.cc | www.y35.vip | www.11fg.com | www.l90.club | www.zz49.com | www.kx25.com | www.fd13.com | www.ks41.com | www.ki81.com | www.zh8.com | 网易彩票www.554313.com | 大赢家彩票平台www.131873.com | 076081.com | 366265.com | 009900.cc | 756706.com | pm71.com | 5524.wang | 385761.com | 970476.com | www.8589.site | www.581274.com | www.561016.com | www.530267.com | www.700452.com | 798012.com | 237764.com | 216182.com | 981487.com | 同乐彩票www.tlcp4.com | 764211.com | 526676.com | 730234.com | 032917.com | 056925.com | 384468.com | 894952.com | 60520.cc | 678834.com | www.9657.loan | www.01257.com | www.13982.com | www.238229.com | www.186742.com | www.222550.com | www.189664.com | www.155820.com | www.465666.com | www.411443.com | www.589596.com | www.553144.com | www.493628.com | www.618667.com | www.954284.com | www.872530.com | www.824776.com | www.791151.com | www.712651.com | www.687905.com | www.623216.com | www.660306.com | www.672826.com | www.666319.com | www.656187.com | www.728636.com | www.671193.com | www.632381.com | www.845017.com | www.930360.com | www.863133.com | www.958164.com | www.870039.com | www.964735.com | www.867060.com | www.869010.com | www.956810.com | www.865342.com | www.833777.com | www.752257.com | www.737108.com | www.654095.com | www.971178.com | www.882533.com | www.980644.com | www.929505.com | www.862301.cc | www.964383.com | www.873196.com | www.955330.com | www.858639.com | www.853976.com | www.850128.com | www.776573.com | www.713533.com | www.640147.com | www.747176.com | www.658123.com | www.712590.com | www.644337.com | www.581367.com | www.509353.com | www.438805.com | www.352763.com | www.571672.com | www.480886.com | www.386544.com | www.385208.com | www.306407.com | www.247472.com | www.166836.com | www.188816.com | www.121139.com | www.044494.com | www.91167.cc | www.33837.cc | www.6543.love | www.1958.cc | www.1896.top | www.2053.vip | www.81gk.com | www.a96.cc | www.gt05.com | www.cp152.com | 312388.com | 205780.com | 504496.com | 76055.com | 721321.com | 375863.com | cp505.com | www.877468.com | www.900520.com | www.789335.cc | www.708842.com | www.675933.com | www.141408.com | 680752.com | www.395142.com | www.907.tv | www.843883.com | www.012385.com | 903560.com | www.146676.com | 977871.com | www.382081.com | www.wl21.cc | www.638508.com | www.6088.cm | www.882544.com | www.93411.com | 4327.biz | www.100163.com | 535334.com | www.229321.com | 396320.com | www.324928.com | 大赢家彩票www.594211.com | www.478889.com | www.ss92.com | www.565942.com | www.02gb.com | www.654107.com | www.5062.cn | www.860693.com | www.078008.com | 363255.com | www.186492.com | 500彩票www.50026s.com | www.453821.com | www.ni64.com | www.655512.com | www.4987.biz | www.831828.com | www.505938.com | www.950537.com | www.99734.com | 803846.com | www.144708.com | 06kx.com | www.402898.com | www.16uk.com | www.652399.com | www.5265.top | www.811225.com | www.44741.com | www.951504.com | www.85017.com | 358847.com | www.202240.com | 040013.com | www.357944.com | www.t53.club | www.610575.com | www.1418.vip | www.858490.com | www.91763.cc | hy49.com | www.069246.com | 110342.com | www.223699.com | 972145.com | www.396965.com | www.43re.com | www.696643.com | www.2011.cn | www.890445.com | www.37821.cc | www.952953.com | www.80338.cc | cai3939.com | www.258887.com | 501159.com | www.368803.com | www.pb42.com | www.602368.com | www.71ia.com | www.713925.com | www.1970.tv | www.875660.com | www.75843.com | 6236.biz | www.121708.com | 67477.cc | www.200532.com | www.bq5.cc | www.511596.com | www.38589.cc | www.950059.com | www.74973.com | 892060.com | www.135484.com | 980547.com | www.320482.com | 全民乐彩票www.2934h.com | www.406321.com | www.xh31.com | www.580211.com | www.23ae.com | www.712972.com | www.60167.com | www.9318.xyz | www.4253.vip | www.982119.com | www.010883.com | ve72.com | www.140096.com | 791744.com | www.333455.com | 尊彩www.083016.com | www.523622.com | www.4912.cm | www.851340.com | www.088915.com | 855265.com | www.171069.com | 财神网www.29277l.com | www.468310.com | www.fd53.com | www.537844.com | www.j45.shop | www.617003.com | www.2166.vip | www.778222.com | www.5284.net | www.809228.com | www.00196.com | www.bf98.com | 499400.com--599500.com | www.628993.com | www.252674.com | 500彩票www.338035.com | www.789674.com | www.369090.com | www.171773.com | www.24971.com | 985342.com | www.544985.com | www.197568.com | www.6711.org | 500彩票www.50054h.com | www.970643.com | www.289895.com | www.4yb.com | 185887.com | www.864466.com | www.507993.com | 500彩票www.50051r.com | www.585129.com | www.009966.com | www.39hx.com | 186077.com | www.861822.com | www.127050.com | www.04532.com | www.dd20.com | 743996.com | www.719025.com | www.041866.com | 170226.com | www.948162.com | www.494163.com | www.279303.com | www.42674.com | www.979672.com | www.554466.com | www.181952.com | www.19661.com | www.ef.com | www.517936.com | www.25221.cc | www.bx62.com | 399111.com | www.654688.com | www.317331.com | www.th25.com | www.05151.com | www.757894.com | www.324255.com | www.62126.cc | www.lf43.com | 587949.com | www.732753.com | 541144.com | www.942180.com | www.831095.cc | www.749652.com | www.690233.com | www.563036.com | www.494109.com | www.627616.com | www.753867.com | www.616464.com | www.818929.com | www.967011.com | www.864432.com | www.947396.com | www.859976.com | www.898808.com | www.790959.com | www.696708.com | www.630016.com | www.625393.com | www.596801.com | www.60154.com | www.b83.xyz | www.775662.com | www.7188.org | www.835179.com | www.999666.com | www.791433.com | www.599510.com | www.393431.com | www.332614.com | www.210221.com | www.107490.com | www.56563.com | www.8646.cc | www.61gj.com | www.bm37.cc | 606205.com | 003569.com | www.981871.com | www.773575.com | www.555905.com | www.368298.com | www.224580.com | www.020470.com | www.39090.com | www.2525.pw | www.uw38.com | 宏发网www.170955.com | 334172.com | www.968027.com | www.734633.com | www.607128.com | www.421382.com | www.339717.com | www.162550.com | www.272932.com | www.072655.com | www.61695.cc | www.12306.cc | www.48ch.com | 彩神网www.csw288.com | 919018.com | www.992181.com | www.gi88.com | 192785.com | vq17.com | www.918196.com | www.679112.com | www.461558.com | www.271600.com | www.081684.com | www.31600.com | www.363.mobi | www.zp98.com | 345003.com | 860177.com | www.953046.com | www.974337.com | www.744430.com | www.526299.com | www.287899.com | www.077499.cc | www.12099.cc | www.39jh.com | 七彩www.53911c.com | wns.am | www.974129.com | www.972953.com | www.738867.com | www.733857.com | www.488900.com | www.237269.com | www.053813.com | www.26539.cc | www.41et.com | 华彩www.71399y.com | 521438.com | www.981450.com | www.794569.com | www.577783.com | www.314180.com | www.096894.com | www.02834.com | www.73nd.com | 幸运彩票www.976500.com | 254398.com | 897568.cc | www.824244.com | www.583210.com | www.337630.com | www.364234.com | www.198753.com | www.95679.cc | www.2634.cm | www.tc47.com | 大发彩票www.www.6hcczz.com | fo32.com | www.880275.com | 712691.com | www.rb29.com | 467056.com | www.939026.com | www.668062.com | www.403837.com | www.323363.com | www.117567.com | www.79633.com | www.9433.vip | www.8yi.cc | 快彩在线www.cpkk.com | 960774.com | www.957576.com | www.679264.com | www.418484.com | www.170573.com | www.84755.cc | www.967.mobi | www.6cy.com | 网易彩票www.082wy.com | 222047.com | www.935908.com | www.767866.com | www.533096.com | www.252695.com | www.018091.com | www.5800.cm | www.wv90.com | 970489.com | 778470.com | www.893386.com | www.608670.com | www.619303.com | www.550080.com | www.289077.com | www.051099.com | www.19810.com | www.30wi.com | www.32238g.com | 734633.com | www.958329.com | www.678831.com | www.388418.com | www.198589.com | www.79118.com | www.14763.com | www.176296.com | www.179422.com | www.016950.com | www.4757.top | www.li03.com | 981524.com | 15ci.com | www.928814.com | www.629488.com | www.534645.com | www.259159.com | www.045287.com | www.6002.cm | www.tw27.com | 81088.cc | www.974651.com | www.687776.com | www.419899.com | www.157099.com | www.095516.com | www.40922.com | www.54nu.com | GO彩www.gai50.com | 632989.com | www.829058.com | www.801869.com | www.522298.com | www.246544.com | www.254944.com | www.038873.com | www.7120.in | www.zd70.com | 93336.cc | 5975.biz | 021829.com | www.811091.com | www.726816.com | www.513295.com | www.252169.com | www.051866.com | www.4635.biz | www.mk08.com | 亚投彩票www.ya044.com | 358547.com | www.897769.com | www.645207.com | www.425605.com | www.145399.com | www.150972.com | www.051566.com | www.6626.cn | www.k66.org | 06qd.com | www.975394.com | www.674188.com | www.379229.com | www.448308.com | www.176331.com | www.88284.com | www.1236.cn | www.yi86.com | 658932.cc | www.959034.com | www.648823.com | www.411818.com | www.219614.com | www.026294.com | www.8928.cn | www.vr48.com | 576470.com | 500835.com | www.770849.com | www.647398.cc | www.523608.com | www.211933.com | www.87234.cc | www.83pq.com | 红鹰彩票www.hy6933.com | 7025.com | www.795099.com | www.485709.com | www.147012.com | www.60098.cc | www.5878.com | www.ng77.com | 万利www.32123h.com | 9015.biz | www.783559.com | www.523964.com | www.216286.com | www.312160.com | www.769422.com | www.544116.com | www.204297.com | www.49561.com | www.94nx.com | www.jv07.com | 200573.com | www.984436.com | www.672488.com | www.340390.com | www.051103.com | www.2973.biz | www.cai7722.com | 127091.com | www.857159.com | 492405.com | www.694.tv | www.hx13.cc | 80448.cc | 00040.cc | www.711432.com | www.472964.com | www.141896.com | www.72288.com | www.57zm.com | 464665.com | www.714122.com | www.189871.com | www.126119.com | www.020526.com | www.253.in | www.cp9558.com | 344600.com | www.881923.com | www.670172.com | www.344244.com | www.018059.com | www.88yg.cc | 网易彩票www.085wy.com | 020875.com | www.760747.com | www.581190.com | www.369495.com | www.108257.com | www.30654.com | www.p14.cc | 964945.com | www.985334.com | www.659845.com | www.713602.com | www.367396.com | www.346383.com | www.127589.com | www.6798.cn | www.oc74.com | 984961.com | 390488.com | www.783381.com | www.438427.com | www.111781.com | www.8733.loan | www.qu98.com | 501960.com | www.921527.com | www.555168.cc | www.243300.com | www.61229.com | www.871.live | www.bq8.com | 722861.com | www.759732.com | www.371677.com | www.136897.com | www.69257.cc | www.894.xyz | www.a30.com | 546484.com | www.895212.com | www.526761.com | www.167286.com | www.012907.com | www.0601.com | 大赢家彩票平台www.377591.com | 009413.com | www.797381.com | www.468089.com | www.308790.com | www.95735.com | www.61695.cc | www.816.la | www.42416.com | www.07mj.com | www.15736.cc | www.191884.com | www.30070.com | www.yo26.com | 599489.com | www.896340.com | www.523744.com | www.135535.com | www.18673.com | www.38080.cc | www.ye99.com | 69xo.com | www.827057.com | www.644889.com | www.520622.com | www.144586.com | www.19812.cc | www.34528.com | www.a19.club | 718312.com | www.897319.com | www.973397.com | www.600540.com | www.211823.com | www.69590.com | www.66uj.com | www.n08.cc | www.97yu.com | www.g24.com | 504499.com | 725697.com | www.748205.com | www.577966.cc | www.751293.com | www.479777.com | www.454245.com | www.305582.com | www.035533.com | www.4736.vip | www.kc61.com | TT彩票www.526053.com | 110172.com | www.903892.com | www.580965.com | www.261517.com | www.026230.com | www.6671.top | www.kr43.com | 544535.com | 156990.com | www.788148.com | www.503221.com | www.205095.com | www.197265.com | www.44233.cc | www.12hy.com | 029036.com | 725655.com | www.815286.com | www.509059.com | www.169796.com | www.201861.com | www.73398.com | www.0597.com | www.jo46.com | 717111.com | 654175.com | www.806570.com | www.505566.cc | www.180525.com | www.080974.com | www.5574.cn | www.wt8.com | 518812.com | www.827136.com | 009695.com | www.781954.com | www.453507.com | www.136140.com | www.69055.com | www.783.me | www.at41.com | 507627.com | www.898017.com | www.563107.com | www.326173.com | www.150483.com | www.028852.com | www.0187.me | www.hr49.cc | 福彩www.16878m.com | 033972.com | www.823995.com | www.560196.com | www.209536.com | www.33908.com | www.zq14.com | dd48.com | www.886694.com | www.576104.com | www.255421.com | www.69515.com | www.32rr.com | 8364.com | www.920723.com | www.568721.com | www.200802.com | www.397432.com | www.124144.com | www.6669.loan | www.am17.com | 137472.com | www.795009.com | www.468336.com | www.140342.com | www.54256.com | www.02od.com | 293160.com | 960480.com | www.837018.com | www.811188.com | www.506212.com | www.346475.com | www.072595.com | www.2576.cn | www.zc16.com | 654663.com | 722330.com | www.837111.com | www.721796.com | www.434147.com | www.184086.com | www.79779.com | www.3201.net | 500万彩票www.936250.com | 907105.com | www.760888.com | www.377468.com | www.265600.com | www.62126.cc | www.2130.vip | www.ls9.com | 026705.com | www.813572.com | www.499867.com | www.121904.com | www.7846.biz | www.ab22.com | 7847.biz | www.811345.com | www.426854.com | www.162243.com | www.022189.com | www.2788.in | 500彩票www.607212.com | 6039.biz | www.111723.com | www.02094.com | www.rm72.com | 688998.com | www.885830.com | www.808022.com | www.498365.com | www.158010.com | www.081103.com | www.3205.vip | www.oz37.com | 240713.com | 05410.com | www.698568.com | www.323223.com | www.445561.com | www.094200.com | www.4214.me | 500彩票网www.864155.com | 669447.com | www.768229.com | www.385345.com | www.368494.com | www.162469.com | www.88676.cc | www.94ol.com | 281893.com | www.973740.com | www.597356.com | www.602726.com | www.462393.com | www.111515.com | www.k24.tv | 295710.com | www.995522.com | www.654853.com | www.333560.com | www.067788.com | www.94pf.com | 363275.com | www.868084.com | www.515993.com | www.128363.com | www.2981.vip | 388888.com | www.935808.com | www.512098.com | www.040034.com | www.48jv.com | 290869.com | www.882637.com | www.766709.com | www.330170.com | www.61731.cc | www.64pp.com | 604268.com | www.877113.com | www.705563.com | www.388421.com | www.067655.com | www.0781.net | 金彩www.985jc.com | www.981565.com | www.586509.com | www.133574.com | www.073898.com | www.96di.com | 大赢家彩票平台www.160886.com | www.969275.com | www.510249.com | www.063429.com | www.80by.cc | 275691.com | www.948061.com | www.509571.com | www.172721.com | www.669601.com | www.194458.com | www.6636.com | www.8910.bid | www.94440.cc | www.7ti.com | 967216.com | www.798633.com | www.723704.com | www.286266.cc | www.26280.cc | 华彩网www.hcw332.com | www.973652.com | www.535823.com | www.088171.com | www.25zi.com | 044608.com | www.916215.com | www.451632.com | www.029956.com | www.29gr.com | 332424.com | www.736651.com | www.298608.com | www.00725.com | www.cai57.cc | www.976942.com | www.522276.com | www.080885.com | www.49cm.com | 504747.com | www.763369.com | www.277800.com | www.22590.com | www.kj2.com | 701707.com | www.660971.com | www.555641.com | www.229066.com | www.8189.wang | 500彩票www.50064x.com | www.957704.com | www.589700.com | www.466589.com | www.052917.com | www.34zl.com | 915973.com | www.675556.com | www.270921.com | www.63805.com | www.9zj.cc | 419234.com | www.739323.com | www.282532.com | www.11381.com | www.cp958.com | 974805.com | www.690759.com | www.231296.com | www.7904.com | 福利彩票www.8039h.com | www.964295.com | www.590648.com | www.221948.com | www.06991.com | 48sw.com | www.958011.com | www.503530.com | www.047818.com | www.34jh.com | 969473.com | www.691671.com | www.205576.com | www.5066.cm | 657237.com | www.931837.com | www.457065.com | www.064937.com | www.28dl.com | 075006.com | www.714342.com | www.224049.com | www.4718.org | 286262.com | www.857989.com | www.457045.com | www.089875.com | www.196.red | 926511.com | www.942524.com | www.449970.com | www.85883.cc | www.zy98.com | 3731.biz | www.593380.com | www.112570.com | www.34xg.com | 984275.com | www.675991.com | www.206181.com | www.21511.cc | www.080610.com | www.30ga.com | pk51.com | www.662917.com | www.349297.com | www.39383.cc | 必发彩票www.760557.com | www.961869.com | www.485336.com | www.8cp.cc | www.508911.com | 彩票3www.cp3.mobi | www.210978.com | 271201.com | www.019077.com | www.rk21.com | 522481.com | www.702658.com | www.178065.com | www.021222.com | www.10ha.com | 959464.com | www.707255.com | www.180658.com | www.11273.cc | 中彩网www.71233k.com | www.883174.com | www.625893.com | www.211586.com | www.3689.xyz | 896350.com | www.877959.com | www.390039.com | www.80001.cc | www.uq68.com | 034896.com | www.612226.com | www.88sw.com | www.563303.com | www.45512.com | www.9yl.com | 652496.com | www.780707.com | www.306439.com | www.36955.com | 大赢家彩票平台www.805681.com | 953701.com | www.627484.com | www.181860.com | www.202249.com | www.7820.org | 爱彩www.1444ac.com | www.947672.com | www.498066.com | www.029089.com | www.10lv.com | www.pjw858.com | www.874362.com | www.634414.com | www.454150.com | www.082866.com | www.30zu.com | yl95.cc | www.819887.com | www.640950.com | www.266581.com | www.98155.com | www.9ue.com | 373021.com | www.757066.com | www.289302.com | www.21234.cc | www.cai9033.com | www.977895.com | www.528179.com | www.095517.com | www.98ol.com | www.7573.pw | www.026959.com | www.8wt.com | 048478.com | www.754428.com | www.507296.com | www.067778.com | www.07tz.com | 110146.com | www.775128.com | www.298365.com | www.77812.com | www.0269.me | www.cai3458.com | www.975485.com | www.530923.com | www.042347.com | www.133.red | 431276.com | www.918654.com | www.397284.com | www.017892.com | www.7ps.com | 604923.com | www.783323.com | www.343663.com | www.71088.com | www.45rf.com | 667225.com | www.708893.com | www.622930.com | www.261537.com | www.8822.link | 68彩票www.68689w.com | www.947134.com | www.585910.com | www.126062.com | www.11012.com | www.bj85.com | www.962681.com | www.393332.com | 630269.com | www.113043.com | www.974634.com | www.5219.net | www.667692.com | www.4459.cn | www.630395.com | www.84um.com | www.550190.com | 好彩头www.51331d.com | www.184891.com | 816897.com | www.148544.com | 772942.com | www.53357.cc | www.817443.com | www.57km.cc | www.522448.com | 791478.com | www.181915.com | 85ds.com | www.200081.cc | 204004.com | www.68304.com | 456054.com | www.06012.com | www.691019.com | www.mv84.com | www.376121.com | 454397.com | www.137501.com | 9161.biz | www.40405.com | www.994681.com | www.7924.me | www.680874.com | www.pj80.cc | www.406679.com | 794511.com | www.161408.com | 976214.com | www.86677.com | www.843522.com | www.5304.cc | www.632096.com | www.wt65.com | www.337114.com | 631288.com | www.019760.com | www.871563.com | www.693762.com | www.259124.com | www.4788.com | 185756.com | www.863250.com | www.635757.com | www.424243.com | www.71531.com | www.vy97.com | 675436.com | www.618234.com | www.209958.com | www.4167.org | 871493.com | www.916065.com | www.620593.com | www.405192.com | www.087583.com | www.66mt.cc | 166258.com | www.749609.com | www.457913.com | www.89344.com | www.jc45.com | 033760.com | www.619601.com | www.312698.com | www.00838.com | 彩82www.c1663.com | www.939349.com | www.403665.com | www.115225.com | www.63xp.com | 815145.com | www.659331.com | www.250399.com | www.7264.org | 984831.com | www.849938.com | www.338251.com | www.03797.com | 8号彩票www.81520f.com | www.910268.com | www.355286.com | www.13301.com | 496205.com | www.874371.com | www.552702.com | www.11078.cc | 23160.com | www.478819.com | www.8983.top | www.f24.link | 010376.com | www.565038.com | www.065239.com | www.23fc.com | 497479.com | www.636568.com | www.192269.com | www.0245.in | 365454.cc | www.908768.com | www.333628.com | www.9399.biz | 378319.com | www.799335.com | www.239923.com | www.99081.cc | www.00978.com | 149178.com | www.830123.com | www.276177.com | www.89374.com | www.8mt.cc | 908554.com | www.583016.com | www.056234.com | www.xk92.com | 109054.com | www.549691.com | www.055850.com | www.k58.org | 83935.cc | www.496400.com | www.97577.cc | www.a14.online | 974256.com | www.663915.com | www.362103.com | www.031303.com | www.mj02.com | 544686.com | www.596347.com | www.5239.xyz | 127361.com | www.806137.com | www.231200.cc | www.405.biz | www.ph09.com | 008364.com | 819702.com | www.22uc.com | 274746.com | www.661784.com | www.202286.com | www.84kj.com | 740171.com | www.758378.com | www.246765.com | www.0528.cc | 647900.com | www.783702.com | www.202593.com | www.0478.org | www.45208.com | www.94nh.com | 891841.com | www.638792.com | www.182502.com | www.0930.love | 484558.com | www.839953.com | www.371253.com | www.61250.com | www.15ar.com | 025641.com | www.501628.com | www.5581.pro | 362885.com | www.694626.com | www.076205.com | www.c99.net | 464949.com | www.525381.com | www.81390.com | www.yi17.com | www.986773.com | www.400338.com | www.035920.com | www.xz98.cc | 55vt.com | www.560067.cc | www.019406.com | www.vh67.com | www.969672.com | www.808026.com | www.370578.com | www.41984.com | 彩票宝www.3cpb.com | www.852325.com | www.402755.com | www.59055.com | www.kp99.cc | 650927.com | www.571018.com | www.020699.com | 大奖彩票www.djcp009.com | www.906717.com | www.303730.com | www.6306.vip | 608899.cc | www.697085.com | www.119552.com | www.s85.club | 943337.com | www.572852.com | www.008181.cc | www.gp91.com | www.949758.com | www.315000.cc | www.6340.cm | 964961.com | www.848665.com | www.478879.com | www.56396.cc | www.nk72.com | 184831.com | www.551215.com | www.69630.com | www.of43.com | www.987820.com | www.402298.com | www.48659.com | www.eq07.com | www.841394.com | www.61ci.com | www.424321.com | 716257.com | www.012357.com | www.827993.com | www.1yd.com | www.369091.com | 070170.com | www.022592.com | www.940768.com | www.467875.com | www.161679.com | www.561208.com | www.43767.com | 575432.com | www.707368.com | www.020428.com | 126342.com | www.666336.com | www.005880.com | 天下彩www.431016.com | www.702923.com | www.96316.com | 853428.com | www.703337.cc | www.019250.com | eu47.com | www.665943.com | www.099763.com | www.cp820.cc | www.756008.com | www.043368.com | www.fp16.com | www.930736.com | www.192903.com | www.do03.com | www.855539.com | www.155405.com | www.82dp.com | www.948173.com | www.201162.com | www.144253.com | www.x63.com | www.883594.com | www.200391.com | www.mp14.com | www.935221.com | www.349332.com | www.3876.cm | 26uo.com | www.328358.com | www.54bv.com | www.970022.com | www.215930.com | 500彩票www.3126n.com | www.178876.com | 527575.com | www.8110.cn | www.711289.com | www.dh58.com | www.257227.com | 237416.com | www.52823.com | www.809803.com | www.34yd.com | www.755711.com | www.136751.com | www.85vo.com | 274598.com | www.515559.com | www.78727.cc | www.83qh.com | www.986447.com | www.446543.com | www.87992.com | 8k彩票www.803242.com | 015666.com | www.502353.com | www.42894.com | www.jv64.com | www.957210.com | www.335396.cc | www.56839.cc | 幸运彩票www.739366.com | www.902375.com | www.288397.com | www.2886.vip | 088088.com | www.798696.com | www.183719.com | www.8823.mobi | www.059698.com | www.ku04.com | 458386.com | www.454955.com | www.33892.com | 691223.com | www.811120.com | www.316200.cc | www.5516.vip | 180389.com | www.646099.com | www.337193.com | www.6070.shop | 172394.com | www.663545.com | www.107977.com | www.ws23.com | www.940409.com | www.298937.com | www.1505.in | 18569.com | www.632029.com | www.443664.com | www.60481.com | www.dm88.cc | www.976288.com | www.353599.com | www.1098.mobi | 883247.com | www.805553.com | www.163747.com | www.8842.cm | 954317.com | www.676900.com | www.266478.com | www.190.cc | 11805.com | www.602277.com | www.91262.com | www.ai21.com | www.839659.com | www.806067.com | www.210327.com | www.27ll.com | 49442.com | www.437006.com | www.13946.com | 457627.com | www.720158.com | www.096076.com | www.rh43.com | www.881542.com | www.222941.com | www.207365.com | www.33gc.cc | www.982633.com | www.308032.com | www.387.vip | 109115.com | www.595361.com | www.008738.com | 福彩网www.60007x.com | www.797676.cc | www.138347.com | www.5bd.com | www.972454.com | www.313107.com | www.426.cn | 281550.com | www.570332.com | www.60821.com | 万利www.32123n.com | www.kh46.com | www.929081.com | www.246294.com | www.73ll.com | www.46111.com | www.397584.com | www.43434.com | 835146.com | www.607958.com | www.75160.com | 500彩票www.50052h.com | www.778644.com | www.102711.com | www.ct43.com | www.906884.com | www.237332.com | www.25pl.com | www.988024.com | www.301067.com | www.69vs.com | www.991661.com | www.439366.com | www.01321.cc | 320010.com | www.618020.com | www.081049.com | www.eo11.com | www.908940.com | www.238781.com | www.33wz.com | www.983337.com | www.554617.com | www.43343.com | www.cai4177.com | www.793559.com | www.102436.com | www.jl56.com | www.909161.com | www.37wb.com | 788742.com | www.338560.com | 495898.com | www.59615.cc | www.701064.com | www.699075.com | www.044990.com | www.cp139.com | www.815664.com | www.139405.com | www.15028.com | 974768.com | www.705052.com | www.088040.com | www.lq64.com | www.921897.com | www.234241.com | www.45bz.com | 900481.com | www.410039.com | www.025555.com | 大赢家彩票网www.544096.com | www.681219.com | www.257937.com | www.0783.xyz | 980530.com | www.538598.com | www.35465.com | 770564.com | www.588827.com | www.52591.cc | 天下彩www.436106.com | www.777165.com | www.407898.com | www.18315.com | 5677.la | www.671295.com | www.027045.com | 500万彩票www.855312.com | www.805738.com | www.136741.com | www.60qf.com | 789473.com | www.360694.com | www.17873.cc | 305709.com | www.585180.com | www.033011.com | www.dz52.com | www.887890.cc | www.263363.com | www.41qi.com | www.994397.com | www.303025.com | www.136.in | 235684.com | www.500091.cc | www.8395.xyz | 23268.com | www.591992.com | www.019412.com | www.vb.com | www.798165.com | www.147583.com | www.01gn.com | www.950991.com | www.298948.com | www.93sl.com | www.991766.com | www.553035.com | www.03315.com | 167123.com | www.660431.com | www.197803.com | www.20mx.com | www.959312.com | www.254736.com | www.u24.mobi | www.954112.com | www.563845.com | www.67859.com | www.du04.com | www.894650.cc | www.205688.com | www.xd90.com | www.941111.com | www.229179.com | www.36zd.com | www.968223.com | www.257572.com | www.7pz.cc | www.948201.com | www.233242.com | www.uy68.com | www.881372.com | 七乐彩票www.qilc5.com | 爱彩www.1777ac.com | www.751698.com | www.103054.com | www.d22.net | www.903750.com | www.173700.com | www.6040.me | 135621.com | www.505234.com | www.5801.pw | 388245.cc | www.565986.com | www.13968.cc | 329382.com | www.526557.com | www.5921.pro | cp846.com | www.444945.com | www.5708.com | 026754.com | www.483179.com | www.030394.com | 亚投彩票www.ya088.com | www.709658.com | www.028774.com | 豪彩VIPwww.9fk.com | www.713788.com | www.91862.com | 339618.com | www.678553.com | www.71581.com | 500彩票www.640477.com | www.742118.com | www.034655.com | 彩票控www.7777ae.com | www.713623.com | www.000656.com | 436228.com | www.684564.com | www.93376.com | 234045.com | www.645883.com | www.093315.com | www.03mq.com | www.952001.com | www.219270.com | www.15gm.com | www.968979.com | www.247811.com | www.008246.com | 013217.com | www.889309.com | www.128256.com | www.ih1.cc | www.810631.com | www.113177.com | www.p24.me | www.917749.com | www.535757.com | www.23761.cc | 428016.com | www.469426.com | www.37817.cc | 095675.com | www.723229.com | www.026488.com | 576803.com | www.697098.com | www.89658.com | 911256.com | www.762153.com | www.101453.com | www.cai5199.com | www.761420.com | www.082001.com | www.cai7896.com | www.762148.com | www.062708.com | 幸运彩票网www.33598m.com | www.690013.com | www.93689.cc | 805956.com | www.574888.com | www.16595.com | 456681.com | www.632344.com | www.205299.com | www.vq71.com | 273539.com | www.468222.com | www.7287.in | 986463.com | www.437871.com | www.29711.cc | 914511.com | www.522235.com | www.32203.com | 949152.com | 970656.com | www.700247.com | www.96236.cc | 439621.com | www.671412.com | www.02639.com | 184989.com | www.427273.com | www.97804.com | 253892.com | www.609167.com | www.36649.com | 656465.com | www.528953.com | www.128627.com | 55彩票www.755901.com | www.750209.com | www.99058.com | 539147.com | www.611243.com | www.69623.com | 爱彩www.013ac.com | www.680782.com | www.393182.com | www.7665.top | 995914.com | www.387414.com | www.5583.cn | 727055.com | www.466841.com | www.3181.biz | 403388.com | www.315195.com | www.12fq.com | www.918200.com | www.188974.com | www.yu29.com | www.872495.com | www.187302.com | www.59fs.com | bs06.cc | www.627925.com | www.169013.com | www.ww09.com | www.833272.com | www.090522.com | QQ彩票www.89894q.com | www.679392.com | www.67177.cc | www.01gw.com | www.878000.com | www.115272.com | 万彩网www.wcp666888.com | www.731247.com | www.026874.com | 网易彩票www.089wy.com | www.690532.com | www.60373.com | 福利彩票www.78700k.com | www.652585.com | www.111674.com | 金凤凰彩票www.449879.com | www.660848.com | www.072223.com | 127051.com | www.536585.com | www.040096.com | www.53827.cc | www.663921.com | www.ov98.com | www.269226.com | www.50750.com | www.695516.com | 云博彩票www.03882.cc | www.041658.com | www.759194.com | www.xg90.com | www.213891.com | www.933603.com | www.1hg.cc | www.255562.com | GO彩www.fo64.com | www.711156.com | www.65855.com | 915653.com | www.597032.com | www.66586.com | 全民汇彩票www.52303d.com | www.689612.com | www.91109.com | www.yd95.com | www.842726.com | www.369814.com | www.1888.in | 2851.biz | www.301270.com | www.1gc.com | www.825058.com | www.052866.com | 快彩在线www.263289.com | www.683782.com | www.62711.com | 500彩票网www.08299.com | www.523468.com | www.e44.shop | www.632671.com | www.75fz.com | www.919449.com | www.19fh.com | www.319035.com | www.cr47.com | 855897.com | www.463654.com | www.301299.com | 彩之家www.11czj.com | www.432370.com | 598675.com | www.74853.com | 232971.com | www.235883.com | 95zh.com | www.414109.com | www.id30.com | www.392007.com | 71lb.com | www.290004.com | 中彩网www.91233b.com | www.425211.com | www.zi60.com | www.662851.com | www.15518.com | www.954813.com | www.80869.cc | www.949656.com | www.8269.vip | www.519092.com | 011900.cc | www.36323.com | www.597582.com | 974875.com | www.96620.com | www.697448.com | 095265.com | www.026926.com | www.698915.com | www.245089.com | www.qj11.com | www.870694.com | www.356367.cc | www.1974.xyz | 679201.com | www.333804.com | www.zw89.com | www.789618.com | www.011145.com | 729434.com | www.496681.com | www.0422.tv | www.977012.com | www.71305.com | www.805519.com | www.br54.com | www.221809.com | www.909795.com | www.l85.com | www.230744.com | 191293.com | www.90866.cc | www.660872.com | www.mq20.com | www.254666.com | www.974089.com | www.09yf.com | www.237634.com | www.911842.com | www.uv12.com | www.325044.com | www.83vp.com | www.877891.com | www.178328.com | www.ji18.com | www.756372.com | www.52420.com | 554058.com | www.358763.com | www.60mw.com | www.870633.com | www.265349.com | www.qa72.com | www.825328.com | www.018126.com | 075306.com | www.346055.com | www.95dl.com | www.886828.com | www.293871.com | www.qj98.com | www.808080.com | www.254962.com | www.ih73.com | www.833358.com | www.94097.com | 226863.com | www.96282.com | 996728.com | www.562655.com | www.2029.red | www.970654.com | www.105383.com | 791082.com | www.521049.cc | www.073.link | 984247.com | www.384640.com | www.1847.cc | 935903.com | www.287757.com | www.mr62.com | www.764581.com | www.49787.com | 4488.love | www.356894.com | www.56mt.com | www.826637.com | www.92141.com | 881403.com | www.506127.com | www.12955.com | 761484.com | www.554753.com | www.798.in | 507906.com | www.324612.com | www.sn10.com | www.721077.com | www.11900.cc | www.974783.com | www.124040.com | www.ci69.com | www.736491.com | www.23685.com | www.em.cc | www.688848.com | www.27575.cc | 602882.com | www.302781.com | www.77xy.cc | www.964961.com | www.112270.com | 37503.com | www.517440.com | www.0911.biz | 0376.loan | www.184200.com | www.tj70.cc | www.870794.com | www.188671.com | www.0919.live | www.922971.com | www.y38.com | www.237429.com | www.970912.com | www.1wm.com | www.226096.com | www.890639.com | www.kt98.cc | www.179701.com | 027390.com | www.4750.biz | www.390070.com | www.021740.com | 016278.com | www.385921.com | www.zc37.cc | www.774297.com | www.46444.com | 8462.vip | www.489565.com | www.11552.cc | 356485.com | www.234100.com | 大赢家彩票平台www.530196.com | www.585239.cc | www.0722.bid | www.962950.com | www.089516.com | 601909.com | www.568011.com | www.0288.me |